Polymer light
emitting diodes (PLEDs) are optoelectronic devices based on small
molecule or polymers that emit light when an electric current
flow through them. A simple PLED consist of a fluorescent polymer
layer sandwiched between two metal electrodes. Under application
of an electric field electrons and holes are injected from the
two electrodes in to the polymer layer, where they meet and recombine
to produce light. They have been developed for application in
flat panel displays. Envision light weight, portable and flexible
flat panel displays that provide visual imagery that is easy to
read, vibrant in colour and less consuming of power.
PLEDs are
light weight, durable power efficient and ideal for portable application.
PLEDs fewer process steps and also use both fewer low cost materials
than LCD displays. PLEDs can replace the current technology in
many applications due to following performance advantages over
LCD s
*Greater brightness
*Faster response time for full motion video
*Full viewing angle
*Lighter weight
*Greater environmental durability
*More power efficiency
*Broader operating temperature range
*Greater cost effectiveness
2. EVELUTION OF PLED
Light Emitting Polymers (LEPs) are semi-conducting devices that
exhibit electroluminescent characteristics. The phenomenon known
as electroluminescence (EL) is caused by the emission of light
generated from the recombination of electrons and holes electrically
injected into a semi-conductor. So far conventional and marketable
electroluminescent devices (ED s) have always been inorganic semi-conductors
but recent developments in the late 1990s are opening the doors
for organic materials. Obtaining organic materials with electroluminescent
properties was first achieved in the 1960s on anthracene crystals
by Pope et al at New York University.
However these early devices had high operating voltages and very
low quantum efficiency thus they did not attract much attention
for two decades. In 1987 a breakthrough was made by Tang and VanSlyke
at Eastman Kodak who, by using multi layers of sublimated organic
molecules, succeeded in reducing the operating voltage dramatically
and increasing the quantum efficiency significantly. Another important
discovery was made in 1990 by Burroughs Et al at Cambridge University
who detected electroluminescence from diodes based on luminescent
conjugated polymers.
Polymer means
many parts. Polymers are very large organic molecules formed by
thousands of repeating units linked together. One can view these
heavy organic molecules (molecular weight between 5,000 and 150,000)
as very long chains mostly made of C-C, C-O and C-N bonds. Polymer
technology has existed for decades.
Use of natural rubber and common plastics such as polythene dates
back to as early as 1820s. However finding polymers with intrinsic
properties of semi-conductors is very recent. In 1967, electrically
conducting polymers from pyrrole, thiopene and furan were characterized
and the electrical conductivity of poly(anilines) noted. The report
in 1977about doping polyacetylene to achieve conductivity opened
up important vistas for chemistry and physics.
Polymer based light-emitting diodes (LEDs) were discovered in
1990 by Friend et al. The first polymer LED used 'poly phenylene
vinylene' (PPV) as the emitting layer. Since 1990 many different
polymers have been shown to emit light under the application of
an electric field (EL). PPV and its derivatives are still the
most commonly used materials, but polythiophenes polyphenylenes,
and polypyridines are now being tested for higher efficiency,
longer lifetime and lower power requirements.
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